Valence Definition in Chemistry

Valence Definition in Chemistry Valence is typically  the number of electrons needed to fill the outermost shell of an atom. Because exceptions exist, the more general definition of valence is the number of electrons with which a given atom generally bonds or number of bonds an atom forms. (Think iron, which may have a valence of 2 or a valence of 3.) The IUPAC formal definition of valence is the maximum number of univalent atoms that may combine with an atom. Usually, the definition is based on the maximum number of either hydrogen atom or chlorine atoms. Note the IUPAC only defines a single valence value (the maximum), while atoms are known to be capable of displaying more than one valence. For example, copper commonly carries a valence of 1 or 2. Example A neutral carbon atom has 6 electrons, with an electron shell configuration of 1s22s22p2. Carbon has a valence of 4 since 4 electrons can be accepted to fill the 2p orbital. Common Valences Atoms of elements in the main group of the periodic table may display a valence between 1 and 7 (since 8 is a complete octet). Group 1 (I) : Na in NaClGroup 2 (II) : Mg in MgCl2Group 13 (III) : Al in AlCl3Group 14 (IV) : C in CO (double bond) or CH4 (single bonds)Group 15 (V) s are N in NH3 and P in PCl5Group 16 (VI) : O in H2OGroup 17 (VII) s: Cl in HCl Valence vs Oxidation State There are two problems with valence. First, the definition is ambiguous. Second, its just a whole number, without a sign to give you an indication of whether an atom will gain an electron or lose its outermost one(s). For example, the valence of both hydrogen and chlorine is 1, yet hydrogen usually loses its electron to become H, while chlorine usually gains an additional electron to become Cl-. The oxidation state is a better indicator of the electronic state of an atom because it has both magnitude and sign. Also, its understood an elements atoms may display different oxidation states depending on the conditions. The sign is positive for electropositive atoms and negative for electronegative atoms. The most common oxidation state of hydrogen is 8. The most common oxidation state for chlorine is -1. Brief History The word valence was described in 1425 from the Latin word valentia, which means strength or capacity. The concept of valence was developed in the second half of the 19th century to explain chemical bonding and molecular structure. The theory of chemical valences was proposed in an 1852 paper by Edward Frankland.